Cyclic Voltammetry of Aqueous CdSO4- N-(benzol [d] thiazol-2-yl)-3-(2-hydroxybenzylidene) hydrazinyl)-3-oxopropanamide (H2BTHB) System at 291.15 K in 50% DMSO-H2O (V/V)

Authors

Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt

Abstract

The electrochemical behavior of cadmium ions on glassy carbon electrodes in two-step processes involves reduction at -0.95V and oxidation at -0.6 VVs. Ag/AgCl electrodes has been reported. The cyclic voltammetry data for cadmium ions using potassium chloride as supporting electrolyte in 50 % Demso-H2O (V/V) shows enhanced currents in the absence and presence of ligand N-(benzol [d] thiazol-2-yl)-3-(2-hydroxybenzylidene) hydrazinyl)-3-oxopropanamide(H2BTHB). Different cyclic voltammetry solvation data were obtained for cadmium ions in the absence and presence of (H2BTHB).The obtained cyclic voltammetry and thermodynamic data prove the complexation reaction between the cadmium ions and the used ligand.

Keywords